•
borane
英:【【bərən】】美:【【bərən】】
英:
美:
常见释义:
n.
【无化】硼烷,【无化】甲硼烷,硼氢化合物
名词复数形式:boranes
1、
borane
poisoning ─── 硼烷中毒
2、metallo-
borane
─── 【化】 金属硼烷
3、hydrazino-
borane
─── 【化】 肼基硼烷
4、organo-
borane
─── 【化】 有机硼烷
5、alkyl
borane
─── 【化】 烷基硼烷
1、corroboration define ─── 确证定义
2、borage seeds ─── 琉璃苣
3、kid rock born free ─── 儿童摇滚出生自由
4、borders moved ─── 边界已移动
5、collaborateur Cartier ─── 卡地亚公司
6、urus lamborghini ─── 管理兰博基尼
7、bonded labor ─── 抵债劳工(指被雇主或债权人强迫劳动以偿还债务的工人);抵债劳动(指被雇主或债权人强迫劳动以偿还债务)
8、swiss born ─── 瑞士出生
9、never boring ─── 从不无聊
10、bordered hessian matrix ─── 有界黑森矩阵
1、poly (p phenylene
borane
) and poly (m phenylene
borane
) are synthesized by the modified organometallic route. ─── 用改进的有机金属路线合成了聚对亚苯基硼和聚间亚苯基硼。
2、Asymmetric hydroboration is a kind of widely applied and valuable reaction, in which
borane
reduction of prochiral ketones reaction is an important method. ─── 不对称催化硼氢化反应是应用广泛且具有工业价值的反应,其中的硼烷还原前手性酮反应有着举足轻重的作用。
3、The Synthesis of Visible Light Photopolymerization Initiators Triphenyl
borane
-n-butly Complex and the Study of Ultraviolet Spectrum ─── 可见光引发剂三苯基正丁基硼化合物的制备及紫外光谱的研究
4、Synthesis of Chiral Amino Alcohols by Enantioselective
Borane
Reduction ─── 不对称硼烷还原合成手性氨基醇
5、Semi-Empirical Calculations of Asymmetric Reduction of Ketosulfone with
Borane
Catalyzed by Qxazaborolidine ─── 噁唑硼烷催化酮砜不对称还原的半经验方法研究
6、Determination of urinary mercury using potassium
borane
reduction-cold atomic absorption spectrometry ─── 硼氢化钾还原-冷原子吸收光谱法测定尿汞
7、and the compound VII is reduced to a compound IX ezetimibe by a
borane
chiral reducing agent. ─── 化合物VII经硼烷类手性还原剂还原为化合物IX依泽替米贝。
8、Thus we cooperate to study the function and mechanism of this catalyst in the asymmetric
borane
reduction reaction, and the following results are obtained. ─── 于是,我们和其合作来深入研究该类配体的不对称催化机制和功能,得到了如下有意义的结果。
9、This paper introduced the synthesis method of norfloxacin by
borane
compound. The product had high quality and good yield(62 %). ─── 介绍了硼螯化合物合成诺氟沙星的方法,收率高(总收率62%以上)。
Thus we cooperate to study the function and mechanism of this catalyst in the asymmetric
borane
reduction reaction, and the following results are obtained.
Both catalyst -
borane
- ketone adducts and catalyst - alkoxy
borane
adducts have four stable structures.
The structual rule of
borane
were advanced based on the number of above electron, we discussed electron structure of
borane
(http://sentencedict.com/
borane
.html), dense
borane
and hetero—
borane
.
The catalyst is a twisted chair structure and reacts with
borane
at the N site of the catalyst to form catalyst
borane
adduct. The formation reaction is exothermic.
The asymmetric reduction of ketosulfone with
borane
catalyzed by oxazaborolidine is computed by means of the semi-empirical MNDO method.
The chiral oxazaborolidines that formed by the reaction of the new ligands above with
borane
can be used in the asymmetry catalytic reaction prochiral ketones.
Asymmetric
borane
reduction of prochiral ketones is a good process to the synthesis of enantiomerically enriched secondary alcohols.
The poly ( p phenylene
borane
) and poly ( m phenylene
borane
) are synthesized by the modified organometallic route.
Both stereo effect and electron effect of
borane
on the activity of ethylene polymerization were investigated.